Download/Embed scientific diagram | Diagrama de Pourbaix del hierro [12] y voltaje en función del pH (línea azul). from publication: Síntesis de nanopartículas. and radionuclide transport in groundwater. The most well-known studies on comprehensive Eh-pH diagrams are those of Pourbaix () and. Brookins ( ). Aluminum E-pH (Pourbaix) Diagram. The E-pH diagram of aluminum is one of the simplest E-pH diagrams. It will be used here to demonstrate how such.

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Pourbaix diagram

The next phase for constructing the aluminum E-pH diagram is to consider all possible reactions between the four chemical species containing aluminum retained for this exercise, i.

Experience is required to find out the extent and form of the corrosion attack that may occur in the corrosion region s of a Pourbaix diagram. Above this line, water will be oxidized to form oxygen gas, and it will usually not be possible to pass beyond this line as long as there is still water present to be oxidized.

While such diagrams can be drawn for any chemical system, it is important to note that the addition of a metal binding agent ligand will often modify the diagram. From Wikipedia, the free encyclopedia. In the following discussion, only four species containing the aluminum element will be considered: These reactions are summarized in the following Table. The equation must be balanced for M, H, O and charge. The vertical axis is labeled E H for the voltage diagarma with respect to the standard hydrogen electrode SHE as calculated by the Nernst equation.

The usefulness of this graphical representation of thermodynamic data for corrosion studies was discussed by Pourbaix who showed three possible states of a metallic material: Diagra,a Read Edit View history. In order to draw the position of the lines with the Nernst equation, the activity of the chemical species at equilibrium must be defined. Sometimes additional lines are drawn for other concentrations.


Wikimedia Commons has media related to Pourbaix diagrams. In many cases, the possible conditions in a system are limited by the stability region of water. However, an additional consideration is necessary to make such diagrams useful for corrosion situations for which the presence of soluble species in dizgrama environment never reaches values of the order of one molar.

Similarly to phase diagrams, they do not allow for reaction rate or kinetic effects. The presence of trace amounts of certain species such as chloride ions can also greatly affect the stability of certain species by destroying passivating layers.

United States Government Printing Office. By using the standard thermodynamic data from the literature, it is possible to calculate that the free energy of reaction is in fact equal to See diagrams at right. The same values should be used for all species present in the system.

Equilibrium reactions of iron in waterIron corrosion productsIron species and their thermodynamic dataRust chemistryRust convertersSteel corrosion.

Immunity means that the metal is not attacked, while corrosion shows that general attack will occur. For the simple case of a thermodynamic system consisting of a metal M and water, various pourbaic equations may be written having the form:. A base-balanced equation can be converted to an acid-balanced equation using the equilibrium constant for the self-ionization of waterand only acid-balanced equations are considered below.

In the conditions of potential and pohrbaix of that region a metal is considered to be totally immune from corrosion attack and safe to use. In these cases, pE is used instead of E H. This page was last edited on 26 Decemberat The reaction equation is found to be:. E-pH diagram of aluminum with four concentrations of soluble species 25 o C.

Predominant ion boundaries are represented by lines. As a function of temperature.

Diagrama de Pourbaix – Wikipedia, la enciclopedia libre

This will vary with temperature. Pourbaix diagrams are widely used to describe the chemical behaviour of chemical species in the hydrosphere.


The apparent stability of the solid species considered gradually recedes as lower values of soluble species are used in the calculations. Using the Pourbaix diagram correctly will help shed light not only on the nature of the species present in the solution or sample but may also help to understand the reaction mechanism.

Diagrama de Pourbaix

A simplified Pourbaix diagram indicates regions of “Immunity”, “Corrosion” and “Passivity”, instead of the stable species. It will be used here to demonstrate how such diagrams are constructed from basic principles.

Pourbaix diagrams have several uses, for example in corrosion studies, geoscience and in environmental studies.

The lines in the Pourbaix diagram show the equilibrium conditions, that is, where the activities are equal, for the species on each side of that line. Archived from the original on Possible reactions in the Al-H 2 O system.

Environmental Chemistry – a global perspective 3rd ed. Vertical, horizontal, and sloped. E-pH diagram of solid species of aluminum when the soluble species are at one molar concentration 25 o C.

Since there is no change in valence of the aluminum present in the two ionic species considered, the associated equilibrium is independent of the potential and the expression of that equilibrium can be derived in the following expression for standard conditions.

Using the expressions for the free energy in terms of potentials, the energy balance is given by a Nernst equation:. The “H” stands for hydrogen, although other standards may be used, and they are for room temperature only.

For instance, carbonate has a great effect upon the diagram for uranium. It is customary to use the lowest boundary 10 -6 as a practical indication of the corrosion stability of a metal and its solid products Figure 4.